6-(1-Methylethyl)-12-phenyl-5,6,7,12-tetrahydrodibenz[c,f][1,5]azasilocine
نویسندگان
چکیده
منابع مشابه
6-(1-Methylethyl)-12-phenyl-5,6,7,12-tetrahydrodibenz[c,f][1,5]azasilocine
The title compound, C(23)H(25)NSi, has an eight-membered silicon-containing heterocyclic ring with an intra-molecular N⋯Si close contact, the transannular distance of which is 2.6294 (18) Å. The resulting geometry about the Si atom is distorted trigonal-bypyramidal, with the N and H atoms occupying apical sites. The dihedral angle between the aromatic rings fused to the eight-membered ring is 6...
متن کاملBis(2-chloro-1-methylethyl)ether.
Data were last reviewed in IARC (1986) and the compound was classified in IARC Monographs Supplement 7 (1987). 1.1.2 Structural and molecular formulae and relative molecular mass C 6 H 12 Cl 2 O Relative molecular mass: 171.7 1.1.3 Physical properties (for details, see IARC, 1986) (a) Boiling-point: 187°C (b) Melting-point: –100°C (c) Conversion factor: mg/m 3 = 7.02 × ppm 1.2 Production, use a...
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As a first example of opening a secondary aziridine with a tertiary carbanion, the title amines (3a-c, aryl = phenyl, 4-tert-butylphenyl,2-naphthyl) were synthesized by opening N-(diphenylphosphinoyl)-7-azabicyclo[4.1.0]heptane, aziridine 1, with the corresponding alpha-potassium isopropylarenes, followed by a hydrolysis of the resulting phosphinamides 2a-c.
متن کاملConfigurational Relationships of Methylethyl
The configurational relationship of dextro-methylethyl carbinol to dextro-lactic acid has been established.’ The establishment of the relationship of the higher members of the homologous series of alcohols to the same reference substance will permit the correlation of the configurations of the alcohols among themselves. The present paper contains a report on the results of the efforts in this d...
متن کامل1-(6-Chloro-2-methyl-4-phenyl-3-quinolyl)ethanone
In the title compound, C(18)H(14)ClNO, the quinoline ring system is approximately planar with a maximum devation of 0.022 (1) Å and forms a dihedral angle of 62.70 (3)° with the phenyl ring. In the crystal, pairs of C-H⋯O inter-molecular hydrogen bonds link neighbouring mol-ecules into inversion dimers, forming R(2) (2)(14) ring motifs. These inversion dimers are stacked along the b axis. The s...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809050909